Update On Refinery Sludge and Petrochemical Waste Project
Waste To Energy, Waste Treatment Add commentsAs mentioned earlier in this blog, PEAT advancing a plasma-arc project for a client in China to treat refinery sludge and petrochemical waste. The plasma-arc plasma gasification system construction is finished and the system is scheduled to continue its commissioning in May & June.
Unlike incineration, where combustion gases are treated at atmospheric pressure, the volume of syngas that is generated in a plasma-arc gasification system is significantly reduced. The smaller flue gas volumes also bring benefits in terms of the scale of downstream air pollution control equipment.
Here is a representative plasma-arc syngas composition for processing 60 kg/hr of petroleum sludge with the following chemical composition
(Carbon: 24.94%, Hydrogen: 3.89%, Nitrogen: 4.19%, Chlorine: 0.18%, Oxygen: 19.15%, Sulfur 0.86%, water 29.49%, inorganics 17.29%) in a plasma thermal destruction and recovery system.
SYNGAS UPSTREAM OF APCD |
Nm3/Hr | Nm3/Hr | Kg/Hr | Kg/Hr | % VOL | % VOL |
CO | 23.48 | 21.25 | 26.88 | 26.55 | 24.22% | 21.67% |
CO2 | 5.82 | 6.14 | 11.53 | 12.05 | 6.01% | 6.26% |
H2 | 32.83 | 32.39 | 2.95 | 2.92 | 33.88% | 33.04% |
N2 | 21.76 | 21.77 | 27.20 | 27.20 | 22.45% | 22.21% |
H2S | 0.40 | 0.36 | 0.56 | 0.55 | 0.41% | 0.37% |
ACID GASES (HCl, HF and HI) | 0.09 | 0.07 | 0.11 | 0.11 | 0.10% | 0.07% |
Particulates and Metal Oxides | 0.60 | 0.98 | 0.30 | 0.52 | 0.62% | 1.00% |
H20 | 11.92 | 15.08 | 11.92 | 12.13 | 12.30% | 15.38% |
TOTALS | 96.92 | 98.05 | 81.45 | 82.03 | 100.00% | 100.00% |
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SYNGAS DOWNSTREAM OF APCD |
Nm3/Hr | Nm3/Hr | Kg/Hr | Kg/Hr | % VOL | % VOL |
CO | 23.48 | 21.24 | 26.88 | 26.55 | 24.20% | 23.41% |
CO2 | 5.82 | 6.14 | 11.53 | 12.05 | 6.00% | 6.76% |
H2 | 32.83 | 32.37 | 2.95 | 2.92 | 33.84% | 35.68% |
N2 | 21.76 | 21.76 | 27.20 | 27.20 | 22.43% | 23.98% |
H2S | 0.00 | 0.00 | 0.00 | 0.01 | 0.00% | 0.00% |
ACID GASES (HCl, HF and HI) | 0.00 | 0.00 | 0.00 | 0.00 | 0.00% | 0.00% |
Particulates and Metal Oxides | 0.01 | 0.02 | 0.01 | 0.01 | 0.01% | 0.03% |
H20 | 13.12 | 9.19 | 13.12 | 7.39 | 13.52% | 10.13% |
TOTALS | 97.02 | 90.73 | 81.68 | 76.13 | 100.00% | 100.00% |
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The refinery waste product contains primarily water, and smaller amounts of non-aqueous liquids and solids, both organic and inorganic. Due to environmental regulations, this industrial waste stream poses significant disposal problems for the oil refineries.
Additionally, an expected plasma waste-to-energy project with a large oil refinery site in India has eight crude storage tanks, each is shutdown every eight years for sludge cleaning. Typically 80-90% of the oil in the sludge can be recovered by agitation and recirculation. However the remaining 10% of residual sludge creates large disposal problems due to stringent regulatory requirements.
The plasma-arc waste-to-energy system is designed to convert via plasma gasification approximately 60 kilograms/hr of this refinery waste into syngas estimated to be almost 600,000 BTU/hr (150,000 kCal/hr).
One Response to “Update On Refinery Sludge and Petrochemical Waste Project”
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May 4th, 2013 at 7:47 PM
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