Jan 21
All of the high temperature boiler/reactors – a key component of the TVRC technology – installed and operating to date required an air permit from the applicable regulatory body. Typically, these systems are designed to comply with emissions levels for particulate matter (150 μg/m3), NOx (0.04 PPMV), SOx (0.03 PPMV) and carbon monoxide (9 PPMV), as well as the other typical reference pollutants as they pertain to air emissions.
Below is a summary of the most recent third party emissions testing conducted on a recently commissioned PTDR plasma-arc, plasma gasification. The test was conducted for medical waste treatment. The summary also compares the results to current United States air emission regulations.
Parameter
(USEPA 23) |
USA – EPA
40 CFR Part 60
Standards of Performance for Stationary Sources and Emission Guidelines for New Sources: HMIWI |
Taiwan – EPA
(Asia reference)
|
PTDR
(corrected to 7% oxygen as per US EPA standards) |
HCl |
15 ppmv |
40 ppmv |
N.D. (D.L. 1.5mg/m3) |
Pb |
1.2 mg/dscm |
2 mg/dscm |
N.D. (D.L. 1μg/m3) |
Cd |
0.16 mg/dscm |
0.3 mg/dscm |
0.02488 |
Hg |
0.55 mg/dscm |
0.3 mg/dscm |
N.D. (D.L. 1μg/m3) |
Particulate matter |
69 mg/dscm |
80 mg/dscm |
30.86 |
Dioxins & Furans |
2.3 ng TEQ/dscm |
0.1 ng TEQ/dscm |
0.057 |
NOX |
250 ppmv |
180 ppmv |
80.26 |
SO2 |
55 ppmv |
150 ppmv |
10.14 |
The following parameters were also tested but were found to be non detectible (Detectible limit in parentheses) Chlorides as Cl (1.4 mg/m3), Ammonia (5 mg/m3), Hydrogen Sulfide (1.4 mg/m3). With regards to Volatile Organic Compounds (VOCs), the testing for Benzene, Ethyl Benzene, Toluene and Xylene were all below the detectible limit (1 mg/m3). Finally, with regards to heavy metals with the exception of cadmium, which is listed above, all were below the detectible limit of 1 μg/m3 (antimony had a detectible limit of 5 μg/m3).
It is worth noting that the above emissions for the PTDR plasma-arc, plasma gasification were measured when the energy recovery system (gas engine was not operating and thus the syngas was thermally oxidized. It is noted that if the syngas is utilized in a gas engine or other syngas utilization equipment, then the only gas emissions associated with the PTDR plasma-arc, plasma gasification system would be the exhaust from that source.
Jan 11
According to the United States Environmental Protection Agency’s “Solid Waste Management and Greenhouse Gases: A Lifecycle Assessment of Emissions and Sinks”, disposing of 650,000 tons per year in a landfill without gas collection, could reduce its Greenhouse Gas (GHG) emissions by about 260,000 Metric Tons Carbon Equivalent (MTCE) per year by managing waste in a mass burn combustor unit. For this preliminary discussion, this equates to 0.40 MTCE/ton avoided from landfilling.
However, the EPA’s document uses a combustion system efficiency of 550 kWh per ton of mixed MSW. The high temperature boiler/reactor system in the TVRC system, which combines a high temperature boiler/reactor with a plasma-arc, plasma gasification sytem, has an efficiency of approximately 690 kWh per ton – 25% greater efficiency; thus the high temperature boiler/reactor has the potential to generate approximately 0.50 MTCE/ton avoided from landfilling or in total up to 82,500 MTCE, when assuming 500 TPD.
Additionally, the EPA estimates greenhouse gas (GHG) emissions range from 10 to 20 million metric tons, depending on the different methods used to estimate the biogenic fraction of MSW. EPA’s eGrid (a database of information on electrical generators in the United States) indicates about 53% of the energy generated by MSW combustion facilities is from biogenic sources and 47% is fossil-fuel derived power. If we take that 53% and presume the same percent of GHG emissions are from biogenic sources, then MSW combustion facilities generate less GHGs than fossil-fuels.
Fuel |
CO2 (lbs per MWh) |
MSW |
1016 |
Coal |
2249 |
Oil |
1672 |
Natural Gas |
1135 |
EPA estimates the GHG savings from WTE to be about 1 on of GHGs saved per ton of MSW combusted.
Jan 04
Any fly ash generated in a Thermal Volume Recovery and Conversion System is converted on-site into a vitrified matrix product, thus converting an unusable by-product from the high temperature boiler/reactor system into a usable end-product.
As previously discussed in this blog section as well as on PEAT’s website, the vitrified matrix could be used in a variety of commercial applications including concrete aggregate, insulation, roadbed/fill construction and even in decorative and non-decorative tiles. Independent laboratory tests (i.e. “TCLP”) have proven that the vitrified matrix does not leach, is totally benign and safe for any re-utilization.
PEAT has conducted a range of testing on this material include Toxicity Characteristic Leaching Procedure (TCLP) tests. A summary of the test results can be seen below when fly ash was processed:
Parameter
|
USA – EPA
( 40 CFR 261.24) Mg/l |
Testing Result
|
Arsenic |
5.0 |
N.D. (D.L 0.002 Mg/l) |
Cadmium |
1.0 |
N.D. (D.L 0.01 Mg/l) |
Chromium |
5.0 |
N.D. (D.L 0.01 Mg/l) |
Lead |
5.0 |
N.D. (D.L 0.01 Mg/l) |
Mercury |
0.2 |
N.D. (D.L 0.002 Mg/l) |
The most recent TCLP results on the vitrified matrix from PEAT’s plasma-arc plasma gasification PTDR system previously located at a China refinery is presented in the below table.
Contaminant |
USA – EPA
(40 CFR 261.24)
Regulatory Level
(mg/L) |
China EPA
Regulatory Level
(mg/L) |
China Refinery
Vitrified Matrix
(mg/L) |
Arsenic |
5 |
5 |
ND < 0.050 |
Barium |
100 |
100 |
0.371 |
Cadmium |
1 |
1 |
ND < 0.008 |
Chromium |
5 |
5 |
ND < 0.017 |
Copper |
|
15 |
8.7 |
Hexavalent Chromium |
|
2.5 |
ND < 0.25 |
Lead |
5 |
5 |
ND < 0.018 |
Mercury |
0.2 |
0.2 |
ND < 0.0005 |
Nickle |
|
|
0.441 |
Selenium |
1 |
1 |
ND < 0.041 |
Silver |
5 |
5 |
ND < 0.013 |
Zinc |
|
|
1.22 |
ND = Not Detectable (detectable limit follows)
NR = Not reported |