Dec 21
As discussed earlier in this blog, a vitrified matrix or slag is the primary solid byproduct of plasma arc waste-to-energy processing. The vitrified matrix from plasma arc processing contains the mineral matter associated with the feed materials in a vitrified form – a hard, glassy-like substance. The amount of matrix produced is a function of how much non-combustible mineral matter is present in the feedstock.
This matrix is the result of operating temperatures within the plasma arc reactor above the melting temperature of the mineral matter. Under these conditions in the plasma arc reactor, non-volatile metals and metal oxides bind together in molten form until it is cooled via natural heat loss or via a pool of water, where it would fracture and granulate.
The compressive strength of a slag sample generated from fly ash from coal-fired power plant as well as some sodium carbonate (fluxing agent) was 480 kg/cm2, while its average mortar strength was tested at 169 kg/cm.
The vitrified matrix or slag generated by plasma arc treatment is primarily made up of silicon dioxide (SiO2), aluminum oxide (Al2O3) and calcium oxide (CaO). Toxicity Characteristic Leaching Procedure (TCLP) tests are designed to determine the mobility of both organic and inorganic analytes present in the slag. The most recent TCLP results on the vitrified matrix from the plasma arc waste-to-energy system located at a China refinery is presented in the below table.
Contaminant
|
USA – EPA
(40 CFR 261.24)
Regulatory Level
(mg/L) |
China EPA
Regulatory Level
(mg/L) |
China Refinery
Vitrified Matrix
(mg/L) |
Arsenic |
5 |
5 |
ND < 0.050 |
Barium |
100 |
100 |
0.371 |
Cadmium |
1 |
1 |
ND < 0.008 |
Chromium |
5 |
5 |
ND < 0.017 |
Copper |
|
15 |
8.7 |
Hexavalent Chromium |
|
2.5 |
ND < 0.25 |
Lead |
5 |
5 |
ND < 0.018 |
Mercury |
0.2 |
0.2 |
ND < 0.0005 |
Nickle |
|
|
0.441 |
Selenium |
1 |
1 |
ND < 0.041 |
Silver |
5 |
5 |
ND < 0.013 |
Zinc |
|
|
1.22 |
ND = Not Detectable (detectable limit follows)
NR = Not reported |
.
Nov 02
PEAT recently finalized the installation of a PTDR-100 Refinery Waste Treatment plasma gasification system for a client in China. This plasma-arc, plasma gasification system, is being sought to treat refinery sludge and petrochemical waste.
Here are some pictures of the plasma-arc system:

Plasma-Arc PTDR-100 Plasma Gasification Reactor

Side view of both skids on the PTDR-100 Plasma Gasification System
The refinery waste product contains primarily water, and smaller amounts of non-aqueous liquids and solids, both organic and inorganic, are by-products of the refining and petrochemical industries. For example, a typical industrial waste stream from an oil refinery operation will contain about 80 percent-by-weight water, about 15 percent-by-weight oil, e.g., hydrocarbons and other non-aqueous liquids, and about 5 percent-by-weight solids. Due to environmental regulations, this industrial waste stream poses significant disposal problems for the oil refineries.
The PTDR plasma-arc waste-to-energy system will convert via plasma gasification approximately 50 kilograms/hr (110 lbs) of this refinery waste into syngas estimated to be almost 600,000 BTU/hr (150,000 kCal/hr).
PEAT International designs advanced plasma-arc, plasma gasification systems. PEAT’s industrial waste treatment plants converts refinery waste into energy and other useful end products.
May 13
PEAT is finalizing the construction on another PTDR-100 Refinery Waste Treatment Plant for a client in China. This plasma gasification system, expected to be commissioned during the later part of June and early July, is being sought to treat refinery sludge and petrochemical waste.
The refinery waste product contains primarily water, and smaller amounts of non-aqueous liquids and solids, both organic and inorganic, are by-products of the refining and petrochemical industries. For example, a typical industrial waste stream from an oil refinery operation will contain about 80 percent-by-weight water, about 15 percent-by-weight oil, e.g., hydrocarbons and other non-aqueous liquids, and about 5 percent-by-weight solids. Due to environmental regulations, this industrial waste stream poses significant disposal problems for the oil refineries.
The PTDR waste-to-energy system will convert via plasma gasification approximately 50 kilograms/hr (110 lbs) of this refinery waste into syngas estimated to be almost 600,000 BTU/hr (150,000 kCal/hr).
PEAT International designs advanced waste to energy & industrial waste treatment plants. PEAT’s industrial waste treatment plants converts refinery waste into energy and other useful end products.